Today I heard a wonderful lecture by Dr. Ulrich Dahmen, Director, National Center for Electron Microscopy on Electron microscopy as an observatory of the nanoworld.
Though the title carried the word “nano”, Dahmen did not confine himself to the nano-world alone; towards very early in his talk for example, he showed a video made by some summer students. The video began with a shot of the glowing green traffic light at the Cedar and Oxford intersection of the University of California, at Berkeley. Then the camera started zooming in by factors of ten to show the LEDs, their internal structure, the optical micrographs, scanning electron micrographs, and, finally transmission electron micrographs to show the atomic arrangement at the Angstrom scale. At the end, it zoomed back to the traffic light to indicate the structures at various levels (and how they build up to some everyday object like the traffic light).
Similarly, at the early stages of his lecture, Dahmen indicated how, in the entire twenty years of its service, the total volume that had been observed at the microscopy centre is one cubic centimetre. To put this number in perspective, Dahmen indicated that in some Aluminium alloys the total number of precipitates in one cubic centimetre is the same as the number of stars in a galaxy (of the order of 1015 , if I remember correct), and the electron microscope is capable of looking at each of these precipitates in greater detail.
Most of Dahmen’s talk revolved around some very interesting microscopic studies on Aluminium-Lead alloys. That embedded lead particles, if small enough in size, can get superheated to even 100 degrees is well known. I have also blogged in the past about vacancy mediated strain accommodation in these systems. However, I did not know about the Brownian motion of liquid lead inclusions (via step nucleation, I understand). The videos of these small lead particles executing random motion was very cool; you can find more information on these studies at this page. I also learnt about some magic shapes effects that occur in these systems due to elastic stress effects; here is the paper in PRL which gives the details of a theory that explains these magic shapes:
Pb Nanoprecipitates in Al: Magic-Shape Effects due to Elastic Strain
J. C. Hamilton, F. Léonard, E. Johnson, and U. Dahmen
Abstract:
We present a theory for size-dependent shapes of Pb nanoprecipitates in Al, introducing the concept of “magic shapes,” i.e., shapes having near-zero homogeneous elastic strains. Our quantitative atomistic calculations of edge energies show their effect on precipitate shape to be negligible, thus it appears that shapes must be due to the combined effect of strain and interface energies. By employing an algorithm for generating magic shapes, we replicate the experimental observations by selecting magic-shape precipitates with interfacial energies less than a cutoff value.
Dahmen also showed how the precipitates shapes of a single grain when it nucleates at the grain boundary have very different characters in the two grains owing to the differences in orientation, and how these differences in the precipitate-matrix interface leads to premelting of incoherent interfaces in these systems. This paper in Philosophical Magazine has some more details on such studies:
Observations of interface premelting at grain-boundary precipitates of Pb in Al
U. Dahmen; S. Hagège; F. Faudot; T. Radetic; E. Johnson
Abstract:
This work reports direct observations showing the effect of size and interface structure on premelting behaviour of nanoscale inclusions. Using in-situ transmission electron microscopy it was possible to observe premelting of individual Pb inclusions in Al, each bounded by two distinctly different topotaxial interfaces. Such particles were generated by precipitating single-crystal Pb inclusions a few tens of nanometres in size at grain boundaries in Al. At equilibrium these particles adopt compound shapes, made from two segments whose shape and interface structure is characteristic of their misorientation with the matrix crystal. Only one of these interfaces premelts. In close agreement with a simple model, the width of the liquid layer depends reversibly on undercooling and interface curvature, and hence on particle size. The observed behaviour confirms previous reports on interface-dependent melting. By observing the selective melting of different interfaces for the first time on individual particles, it was possible to rule out experimental uncertainties and to show unambiguously that inclusion melting depends strongly on interface structure.
Finally, Dahmen went on to describe the next generation transmission electron microscopes, known as TEAM — Transmission Electron Aberration-corrected Microscope, which are free of spherical and chromatic aberrations, and hence can achieve half-an-Angstrom resolution, which, Dahmen indicated, is, in a way, an answer to a challenge posed by Feynman nearly fifty years ago:
The electron microscope is not quite good enough, with the greatest care and effort, it can only resolve about 10 angstroms. I would like to try and impress upon you while I am talking about all of these things on a small scale, the importance of improving the electron microscope by a hundred times. It is not impossible; it is not against the laws of diffraction of the electron. The wave length of the electron in such a microscope is only 1/20 of an angstrom. So it should be possible to see the individual atoms. What good would it be to see individual atoms distinctly?
We have friends in other fields—in biology, for instance. We physicists often look at them and say, “You know the reason you fellows are making so little progress?” (Actually I don’t know any field where they are making more rapid progress than they are in biology today.) “You should use more mathematics, like we do.” They could answer us—but they’re polite, so I’ll answer for them: “What you should do in order for us to make more rapid progress is to make the electron microscope 100 times better.”
On the whole, it was a great talk — I enjoyed every minute, every micrograph and every movie of it. It is a pity that we do not record them and post them to YouTube!