The relative misorientation between two grains across a grain boundary is the rotation of one of the crystals such that it is brought into the same orientation as the other; such a rotation is completely described by the rotation angle and the axis about which the rotations are carried out.
The rotations can be decomposed into a tilt and a twist rotation. Tilt is a rotation about an axis that lies in the plane of the boundary. Twist is a rotation about an axis that is perpendicular to the boundary plane. This is the tilt-twist description of the grain boundaries.
Consider a tilt boundary; that is a boundary which is completely described by a tilt angle (say, theta). Further, let the tilt angle be small (i.e., less than 15 deg). The energy (E_tilt_boundary) of such a tilt grain boundary is given by by the Read-Shockley equation:
E_tilt_boundary = C theta (A - ln(theta))
where, C and A are constants.
All this is well known and is described in many text books. However, what is not described is the following:
- How far is this description of tilt boundaries is correct? Are there experimental evidence to show that Read-Shockley equations hold?
- What is the dependence of the grain boundary energy on the boundary plane? In other words, will a tilt a boundary about the <111> axes and <100> axes in a cubic material, for example, have the same energy?
These two questions, and one more (namely, the dependence of the relative mobility of a low-angle grain boundary on the boundary plane) are answered in this paper by Yang, Rollet and Mullins:
- The variation of low-angle grain boundary energy does indeed follow the Read-Shockley expression;
- There is a small dependence of energy on the misorientation angle, with axes closer to <100> having the highest energy and those close to <111> the lowest; and,
- The boundaries with misoreintation closer to <111> are relatively more mobile than those closer to <100>.
These, and other information on grain boundary structure and energetics are also described in Recrystallisation and related annealing phenomena by Humphreys and Hatherly.